Abstract: For some materials and biological samples, free radicals can be induced after ionizing radiation. Electron spin resonance(ESR)spectroscopy can detect free radical signal and its intensity can reflect the dose of the ionizing radiation. It is a typical way to estimate the radiation dosimetry by using the ESR spectroscopy of teeth. In recent years, many researchers studied on ESR of easy-getting materials such as finger(toe) nail, hair, cell phone screen, in order to investigate the relationship between signal intensity and radiation dose. The aim of this paper is to survey the current literature about methodologies and the materials on background signal, linearity of dose-response relationship, minimum detection limit and post-irradiation signal stability, so that more data will be provided for nuclear accident dose estimation.